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http://nopr.niscpr.res.in/handle/123456789/56378
Title: | Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation |
Authors: | Thomas, Raji Jose, Densely Joseph, Nelson P Pardasani, R T Mukherjee, T |
Keywords: | Ti(IV)/Zr(IV) complex;Oxime complex;Amide complex;Hydrated electron;Pulse radiolysis |
Issue Date: | Mar-2021 |
Publisher: | NISCAIR-CSIR, India |
Abstract: | Complexes of the general formula Cp2Ti(IV)L, Cp2Zr(IV)L, Cp2Ti(IV)L1 and Cp2Zr(IV)L1 have been synthesized with N,N’-bis(2-pyridyl)pyridine-2,6-dicarboxamide (H2L) and 9,10-phenanthrenequinone dioxime (H2L1). The complexes have been characterized by different spectral techniques and their reduction reactions have been carried out with hydrated electron as reducing radical, mechanism which has been explored pulse radiolytically. Theoretical calculations have been performed to understand the effect of chelation and electron transfer processes in complexes. |
Page(s): | 361-369 |
ISSN: | 0975-0975(Online); 0376-4710(Print) |
Appears in Collections: | IJC-A Vol.60A(03) [March 2021] |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
IJCA 60A(3) 361-369.pdf | Main Article | 644.55 kB | Adobe PDF | View/Open |
IJCA 60A(3) 361-369_Suppl Data.pdf | Supplementary Data | 564.01 kB | Adobe PDF | View/Open |
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