Synthesis and structure characterization of [Co(H2O)2(DMSO)2(4-nba)]4-nba (DMSO = dimethylsulfoxide; 4-nba = 4-nitrobenzoate)

Abstract

Dissolution of a fine powder obtained by mechanochemical grinding of cobaltous carbonate with 4-nitrobenzoic acid (4-nbaH) in hot dimethylsulfoxide (DMSO) followed by slow evaporation of the solvent resulted in the formation of <em>cis</em>-diaquabis(dimethylsul-foxide)4-nitrobenzoatocobalt(II) 4-nitrobenzoate <strong>1 </strong>in good yield. The title compound [Co(H₂O)₂(DMSO)₂(4-nba)]4-nba <strong>1</strong> crystallizes in the centrosymmetric monoclinic <em>P</em>2₁<em>/c</em> space group. The structure of <strong>1</strong> consists of two crystallographically independent Co(II) ions. Each unique cobalt exhibits octahedral geometry and is bonded to a pair of terminal aqua ligands situated<em> cis</em> to each other and a bidentate 4-nba ligand which form the square base of the octahedron. A pair of DMSO ligands disposed <em>trans</em> to each other complete the hexa coordination around the central metal. The [Co(H₂O)₂(DMSO)₂(4-nba)]⁺ cations and the 4-nba anions are interlinked with the aid of several weak H-bonding interactions. A comparative study of several 4-nitrobenzoate compounds of cobalt is described.