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http://nopr.niscpr.res.in/handle/123456789/46747| Title: | Kinetics of Ce(IV) oxidation of ortho- and meta-methoxymandelic acids in , sulfuric-perchloric acid media |
| Authors: | Sarac, A Seza Gocmen, Ayten |
| Issue Date: | Jul-1989 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of oxidation of o-, and m-methoxy-mandelic acids to the corresponding methoxyben-zaldehydes by Ce(IV) has been studied spectrophotometrically in H2SO4-HCIO4 media, in the range of 0.08-0.42 mol dm-3 HSO , at ionic strength of 2.0 mol dm-3. In H2SO4-HClO4 media, concentration distribution of Ce(IV) sulfate complexes was computed and their correlation with the observed rate constants are discussed. The overall rate constants for o-, and m-methoxy-mandelic acids have been calculated. |
| Page(s): | 602-605 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.28A(07) [July 1989] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 28A(7) 602-605.pdf | 2.11 MB | Adobe PDF | View/Open |
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