Please use this identifier to cite or link to this item: http://nopr.niscpr.res.in/handle/123456789/46705
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dc.contributor.authorSubramani, K-
dc.contributor.authorSrinivasan, Vangalur S-
dc.date.accessioned2019-03-26T06:31:04Z-
dc.date.available2019-03-26T06:31:04Z-
dc.date.issued1989-05-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://nopr.niscair.res.in/handle/123456789/46705-
dc.description378-381en_US
dc.description.abstractThe rates of photo reduction of pentaamminecobalt(III) complexes of ɑ-hydroxy acids at 254 nm are comparable to the rates of formation of cobalt(II) and the corresponding carbonyl product. This is suggestive of electron transfer to cobalt(III) and C-C bond cleavage in an almost concerted manner. The charge transfer to metal ion has an excited state as t facilitating photoreduction of cobalt/Ill). The d - π back bonding is ligand-centered, favouring C-C bond cleavage. In all these reactions, the quantum yield of Co2+ is nearly 0.24.en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.28A(05) [May 1989]en_US
dc.titlePhotoinduced electron transfer in pentaamminecobalt(III) complexes of ahydroxy Acidsen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.28A(05) [May 1989]

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