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DC Field | Value | Language |
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dc.contributor.author | Subramani, K | - |
dc.contributor.author | Srinivasan, Vangalur S | - |
dc.date.accessioned | 2019-03-26T06:31:04Z | - |
dc.date.available | 2019-03-26T06:31:04Z | - |
dc.date.issued | 1989-05 | - |
dc.identifier.issn | 0975-0975(Online); 0376-4710(Print) | - |
dc.identifier.uri | http://nopr.niscair.res.in/handle/123456789/46705 | - |
dc.description | 378-381 | en_US |
dc.description.abstract | The rates of photo reduction of pentaamminecobalt(III) complexes of ɑ-hydroxy acids at 254 nm are comparable to the rates of formation of cobalt(II) and the corresponding carbonyl product. This is suggestive of electron transfer to cobalt(III) and C-C bond cleavage in an almost concerted manner. The charge transfer to metal ion has an excited state as t facilitating photoreduction of cobalt/Ill). The d - π back bonding is ligand-centered, favouring C-C bond cleavage. In all these reactions, the quantum yield of Co2+ is nearly 0.24. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | NISCAIR-CSIR, India | en_US |
dc.rights | ![]() | en_US |
dc.source | IJC-A Vol.28A(05) [May 1989] | en_US |
dc.title | Photoinduced electron transfer in pentaamminecobalt(III) complexes of ahydroxy Acids | en_US |
dc.type | Article | en_US |
Appears in Collections: | IJC-A Vol.28A(05) [May 1989] |
Files in This Item:
File | Description | Size | Format | |
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IJCA 28A(5) 378-381.pdf | 2.16 MB | Adobe PDF | View/Open |
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