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http://nopr.niscpr.res.in/handle/123456789/46106| Title: | Investigations of iron adducts of C60: Novel FeC60 in the solid state with Fe inside the C60 cage |
| Authors: | Pradeep, T Kulkarni, G U Kannan, K R Vasanthacharya, N Y Row, T N Guru Rao, C N R |
| Issue Date: | May-1992 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | By carrying out contact-arc vaporization of graphite in a partial atmosphere of Fe(CO)5 an iron adduct with C60 has been obtained. The adduct has been characterized by various techniques including mass spectrometry, 57Fe Mossbauer spectroscopy and Fe K-EXAFS. Properties of this adduct are compared with those of an adduct prepared by solution method where Fe is clearly outside the cage. Results suggest that FeC60 obtained from the gas phase reaction has the Fe atom in the cage. |
| Page(s): | F17-F21 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC Vol.31A&B(05) [May 1992] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 31A&B(5) F17-F21.pdf | 440.36 kB | Adobe PDF | View/Open |
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