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http://nopr.niscpr.res.in/handle/123456789/44082| Title: | Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium |
| Authors: | Saxena, Rashmi Upadhyay, S K |
| Issue Date: | Dec-1993 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The kinetics of oxidation of palladium(II) catalysed oxidation of some hydroxyacids, viz, malic, citric and tartaric acids by N- bromosuccinimide have been studied in perchloric acid medium in the presence of mercuric acetate. A first order dependence of rate each in [oxidant] and [catalyst] has been observed. The order of reaction in substrate decreases at higher [substrate]. A retarding effect of [H+] on the rate has also been observed. A suitable mechanism consistent with observed kinetic data is proposed and discussed. |
| Page(s): | 1060-1063 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.32A(12) [December 1993] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 32A(12) 1060-1063.pdf | 285.24 kB | Adobe PDF | View/Open |
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