Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/22071| Title: | Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII) |
| Authors: | Rani, D Freeda Gnana Pushparaj, FJ Maria Alphonse, I Rangappa, K S |
| Issue Date: | Oct-2002 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Kinetics of Os(VIII) catalysed oxidation of substituted and unsubstituted 4-oxoacids by alkaline hexacyanoferrate(III) in sodium carbonate-bicarbonate buffer have been studied. The reaction is zero order in oxidant, first order with respect to Os(VIII), first order at higher concentrations and zero order at lower concentrations with respect to both substrate and alkali. The activation parameters have been computed. |
| Page(s): | 2153-2159 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.41B(10) [October 2002] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 41B(10) 2153-2159.pdf | 992.19 kB | Adobe PDF | View/Open |
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.