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Title: | Synthesis, structure and reactivity of palladated azo-oxime-carboxylates |
Authors: | Pal, Chandan Kumar Mukherjee (Karmakar), Soma Ganguly, Sanjib |
Issue Date: | Jan-2001 |
Publisher: | NISCAIR-CSIR, India |
Abstract: | The bidentate ligands H2L(1) react with sodium tetrachloropalladate to form a presumably dimeric species [PdL]2 which on further treatment with triphenyl phosphine or n-butyl amine furnishes adducts of types [PdL(PPh3)] or [PdL(nBuNH2)] respectively. The X-ray structure of [PdL2(PPh3)] has been determined, revealing the square planar PdN2OP geo metry. |
Page(s): | 90-94 |
ISSN: | 0975-0975(Online); 0376-4710(Print) |
Appears in Collections: | IJC-A Vol.40A(01) [January 2001] |
Files in This Item:
File | Description | Size | Format | |
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IJCA 40A(1) 90-94.pdf | 873.4 kB | Adobe PDF | View/Open |
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