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http://nopr.niscpr.res.in/handle/123456789/20974| Title: | Nitrite linkage isomerization promoted by alkyne insertion in ruthenium organometallics |
| Authors: | Chattopadhyay, Swarup Ghosh, Kaushik Pattanayak, Sujay Chakravorty, Animesh |
| Issue Date: | Jan-2001 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The title transformation is of type η2-nitrite → η1 nitrite and it occurs upon reacting carbonyl(η2-nitrito)[4-methyl-6-(N-p-tolyl-imino)phenol] bis (triphenylphosphine) ruthenium(II) with acetylene in warm CH2Cl2-MeOH medium affording carbonyl (η1-nitrito) [2- vinyl -4- methyl -6-(N-p-tolyl-imino) phenolato] bis(triphenylphosphine) ruthenium(II) in which the iminium function is involved in weak bifurcated hydrogen bonding with phenolato oxygen and a nitrite oxygen atom. |
| Page(s): | 1-3 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.40A(01) [January 2001] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 40A(1) 1-3.pdf | 494.17 kB | Adobe PDF | View/Open |
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