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http://nopr.niscpr.res.in/handle/123456789/20067| Title: | Precursors for mixed metal oxide nanoparticles: Synthesis and characterization of μ -oxoalkoxides of some bivalent metals and their β-diketonates |
| Authors: | Sharma, Malti Bhagi, Ajay K Sharma, Harish K Priti Kansal, Ritu Kumar, Ram Kapoor, Pramesh N |
| Issue Date: | Feb-2005 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int.Cl.7 C07F 3/08: C07F 7/22: C07F 7/24: C07F 5/00 |
| Abstract: | New heterobimetallic derivatives of the type M {OA1(OPri)2}2 (M = Sn, Pb, Cd) have been prepared by the reactions of M(OAc)2 with Al(OPri)3 in 1:2 molar ratio in hydrocarbon solvent (xylene/toluene) with the continuous liberation of isopropyl acetate. Furthermore, reactions of M {OA1(OPri)2}2 (M = = Ca, Pb, Cd) with β-diketones (acetylacetone, benzoyl acetone) have also been carried out to obtain modified derivatives. These new derivatives have been characterized by elemental analyses and spectroscopic [IR, NMR (1H,13C, 27Al and 119Sn)] studies. |
| Page(s): | 256-260 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Appears in Collections: | IJC-A Vol.44A(02) [February 2005] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 44A(2) 256-260.pdf | 1.18 MB | Adobe PDF | View/Open |
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