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Title: Reactivity of triphenyltin(IV) O,O'-dialkyl/alkylene dithiophosphates with Lewis bases
Authors: Srivastava, S K
Yadav, R S
Gaur, A
Dubey, N
Issue Date: Feb-2006
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.8 C07F7/22
Abstract: The interactions of triphenyltin(IV) O,O'-dialkyl/alkylene dithiophosphates, [(C6H5)3SnS(S)P(OR)2] and [(C6H5)3SnS(S) IPOGOI] [R= -CH(CH3)2, -CH2CH2OCH3 ; G= -CH2C(CH3)2CH2-, -CH2C(CH3)2CHCH (CH3)2] with various S-,O- and N- donor Lewis bases yield several new molecular adducts. On the basis of elemental analysis and spectral (IR, 1H and 31P NMR) data, the presence of five- and six-coordination of Sn atom in case of unidentate and bidentate Lewis bases, respectively is concluded.
Page(s): 394-397
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.45A(02) [February 2006]

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