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Title: Synthesis and tandem free-radical cyc1ization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl- 6, 10-dodecadiendioate with Mn(III) acetate
Authors: Petrovic, Zorica D
Konstantinovic, S
Scheffold, R
Issue Date: Dec-1999
Publisher: NISCAIR-CSIR, India
Abstract: The synthesis and tandem free- radical cyclization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl-6,10-dodecadiendioate 1 with Mn(OAc)3 are described. The unsaturated β-ketodiester 1 has been prepared from geraniol in six steps and then subjected to the reaction with Mn(OAc)3  giving the bicyclo compounds 10 and 11 in 35% and 45% yields, respectively. The reaction has been carried out under mild conditions and can be very useful method for the synthesis of the desired bicyclo compounds.
Page(s): 1364-1367
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.38B(12) December 1999]

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