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http://nopr.niscpr.res.in/handle/123456789/16668| Title: | Synthesis and tandem free-radical cyc1ization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl- 6, 10-dodecadiendioate with Mn(III) acetate |
| Authors: | Petrovic, Zorica D Konstantinovic, S Scheffold, R |
| Issue Date: | Dec-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The synthesis and tandem free- radical cyclization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl-6,10-dodecadiendioate 1 with Mn(OAc)3 are described. The unsaturated β-ketodiester 1 has been prepared from geraniol in six steps and then subjected to the reaction with Mn(OAc)3 giving the bicyclo compounds 10 and 11 in 35% and 45% yields, respectively. The reaction has been carried out under mild conditions and can be very useful method for the synthesis of the desired bicyclo compounds. |
| Page(s): | 1364-1367 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.38B(12) December 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(12) 1364-1367.pdf | 720.93 kB | Adobe PDF | View/Open |
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