Please use this identifier to cite or link to this item:
http://nopr.niscpr.res.in/handle/123456789/16403| Title: | Chemoselective electrooxidation of (E)-1- phenyl-2- (phenylthio)ethylene and 1-phenyl-2-(phenylthio )acetylene |
| Authors: | Ramalingam, S Perumal, S Selvaraj, S Sivasubramanian, S |
| Issue Date: | Apr-1999 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Electrooxidation of (E)-1-phenyl-2-(phenylthio)ethylene and 1- phenyl-2-(phenylthio)acetylene on glassy carbon electrode in aceto nitrile medium results in the formation of the corresponding sulphones chemoselectively leaving the unsaturated linkages intact. These results are in contrast to the electrooxidation at platinum electrode wherein the scission of the C-S bond of these sulphides also occurs affording different products. |
| Page(s): | 466-469 |
| Appears in Collections: | IJC-B Vol.38B(04) [April 1999] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 38B(4) 466-469.pdf | 1.77 MB | Adobe PDF | View/Open |
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