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dc.contributor.authorDhayal, Rajendra Singh-
dc.contributor.authorJoseph, Ponniah S-
dc.contributor.authorSahoo, Satyanarayan-
dc.contributor.authorGhosh, Sundargopal-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractReaction of Cp#MCl4, (1 or 2) [(1): M = Mo, Cp# = Cp* (Cp* = 5-C5Me5) and (2): M = W, Cp# = Cp (Cp = 5-C5H5)] with excess of [LiBH4.thf] followed by thermolysis with excess of [HS(CH2)nSH] (n = 2 or 3), leads to the formation of [(Cp*Mo)2B4H4S2] (3) or [(CpW)2B4H4S2] (4) respectively. Corresponding to (3) and (4), the compounds [(M)2B5H9] (M = CpW, (5) or Cp*Mo, (6)) are isolated as major product in both the cases. These new compounds have been characterized in solution by mass, 1H, 11B, 13C NMR spectroscopy. The structural types have been unequivocally established by X-ray crystallographic analysis of compounds (4).en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.50A(09-10) [September-October 2011]en_US
dc.subjectCoordination Chemistryen_US
dc.subjectOpen cage compoundsen_US
dc.subjectMetallaheteroborane clustersen_US
dc.titleSynthesis and structural characterization of an open cage dithiatungstaborane [(CpW)2B4H4S2] clusteren_US
Appears in Collections:IJC-A Vol.50A(09-10) [September-October 2011]

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