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Title: Correlation analysis in the reactions of benzyl bromide with N-substituted anilines
Authors: Reddy, S Ranga
Rao, B Rajeswara
Manikyamba, P
Issue Date: Mar-2007
Publisher: CSIR
Abstract: The nucleophilic substitution reaction between benzyl bromide and N-substituted anilines in methanol medium suggests that the reactivity of the nucleophiles increases with their pkb values. A linear relationship exists between the rate and the computed values of the dipole moment and electronegativity of the nucleophiles. The frontier orbital interactions and correlation of rate with HOMO-LUMO gap of the two reactants suggest that the reaction is not orbital controlled but is controlled by the electrostatic interactions between the reactants.
Page(s): 436-439
ISSN: 0376-4710
Appears in Collections:IJC-A Vol.46A(03) [March 2007]

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