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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(03) [March 2007] >
| Title: | Correlation analysis in the reactions of benzyl bromide with N-substituted anilines |
| Authors: | Reddy, S Ranga
Rao, B Rajeswara
Manikyamba, P |
| Issue Date: | Mar-2007 |
| Publisher: | CSIR |
| Abstract: | The nucleophilic substitution reaction between benzyl bromide and N-substituted anilines in methanol medium suggests that the reactivity of the nucleophiles increases with their pkb values. A linear relationship exists between the rate and the computed values of the dipole moment and electronegativity of the nucleophiles. The frontier orbital interactions and correlation of rate with HOMO-LUMO gap of the two reactants suggest that the reaction is not orbital controlled but is controlled by the electrostatic interactions between the reactants. |
| Page(s): | 436-439 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(03) [March 2007]
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