NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(03) [March 2007] >

Title: Correlation analysis in the reactions of benzyl bromide with N-substituted anilines
Authors: Reddy, S Ranga
Rao, B Rajeswara
Manikyamba, P
Issue Date: Mar-2007
Publisher: CSIR
Abstract: The nucleophilic substitution reaction between benzyl bromide and N-substituted anilines in methanol medium suggests that the reactivity of the nucleophiles increases with their pkb values. A linear relationship exists between the rate and the computed values of the dipole moment and electronegativity of the nucleophiles. The frontier orbital interactions and correlation of rate with HOMO-LUMO gap of the two reactants suggest that the reaction is not orbital controlled but is controlled by the electrostatic interactions between the reactants.
Page(s): 436-439
ISSN: 0376-4710
Source:IJC-A Vol.46A(03) [March 2007]

Files in This Item:

File Description SizeFormat
IJCA 46A(3) (2007) 436-439.pdf98.08 kBAdobe PDFView/Open
 Current Page Visits: 765 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 166449 since 01-Sep-2015  Last updated on 28-Jun-2016Webmaster: