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Title: | Correlation analysis in the reactions of benzyl bromide with N-substituted anilines |
Authors: | Reddy, S Ranga Rao, B Rajeswara Manikyamba, P |
Issue Date: | Mar-2007 |
Publisher: | CSIR |
Abstract: | The nucleophilic substitution reaction between benzyl bromide and N-substituted anilines in methanol medium suggests that the reactivity of the nucleophiles increases with their pkb values. A linear relationship exists between the rate and the computed values of the dipole moment and electronegativity of the nucleophiles. The frontier orbital interactions and correlation of rate with HOMO-LUMO gap of the two reactants suggest that the reaction is not orbital controlled but is controlled by the electrostatic interactions between the reactants. |
Page(s): | 436-439 |
URI: | http://hdl.handle.net/123456789/971 |
ISSN: | 0376-4710 |
Appears in Collections: | IJC-A Vol.46A(03) [March 2007] |
Files in This Item:
File | Description | Size | Format | |
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IJCA 46A(3) (2007) 436-439.pdf | 98.08 kB | Adobe PDF | View/Open |
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