Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/9709
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dc.contributor.authorSrikrishna, A-
dc.contributor.authorAnebouselvy, K-
dc.date.accessioned2010-06-08T05:40:04Z-
dc.date.available2010-06-08T05:40:04Z-
dc.date.issued2010-06-
dc.identifier.urihttp://hdl.handle.net/123456789/9709-
dc.description776-788en_US
dc.description.abstractEnantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkyation and Criegee fragmentation are employed for intramolecular stereospecific transfer of the chirality. An intramolecular diazoketone cyclopropanation and regioselective cyclopropane ring cleavage reactions have been employed for the creation of the three requisite contiguous quaternary carbon atoms.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.sourceIJC-B Vol.49B(06) [June 2010]en_US
dc.subjectThapsiaen_US
dc.subjectthapsaneen_US
dc.subjectsesquiterpeneen_US
dc.subjectenantiospecificen_US
dc.titleEnantiospecific total synthesis of ent-5-senecioyloxy-10,11-epoxythapsan-10-olen_US
dc.typeArticleen_US
Appears in Collections:IJC-B Vol.49B(06) [June 2010]

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