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|Title:||Temperature dependent densities of mixtures of 1-butyl-3-methylimidazolium hexafluorophosphate + poly(ethylene glycol)|
|Abstract:||Densities of 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF<sub>6</sub>]) + poly(ethylene glycol) (average molar mass 200 g mol<sup>–1</sup>) [PEG200] mixtures have been measured over the entire composition regime in the temperature range of 283.15–363.15 K at 10 degree intervals, using a density meter based on electromagnetically induced oscillations of a U-shaped glass tube and an inbuilt Peltier thermostat. The density versus temperature data of [bmim][PF<sub>6</sub>] + PEG200 mixtures at each composition have been fitted to a simple linear equation : <img src='/image/spc_char/po.gif'>. The fits are observed to be satisfactory at each composition. The excess molar volumes of [bmim][PF<sub>6</sub>] + PEG200 mixtures are observed to be negative and significant over the entire composition range. Irrespective of the temperature, the maximum absolute excess molar volumes are observed in PEG-rich region at <i>X</i><sub>[bmim][PF6] </sub>~ 0.3. Importantly, the absolute values of excess molar volumes for [bmim][PF<sub>6</sub>] + PEG200 mixtures appear to increase slightly with increasing temperature. These observations are attributed to the presence of strong interactions within the [bmim][PF<sub>6</sub>] + PEG200 mixtures. Specifically, they are proposed to be due to the presence of extensive intermolecular H-bonding involving C2 hydrogen of [bmim<sup>+</sup>] and termini –OH as well as ethoxy –O– of PEG200 within [bmim][PF<sub>6</sub>] + PEG200 mixtures.|
|Appears in Collections:||IJC-A Vol.49A(05-06) [May-June 2010]|
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