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NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Pure & Applied Physics (IJPAP) >
IJPAP Vol.42 [2004] >
IJPAP Vol.42(11) [November 2004] >
| Title: | Three electron bonding in thiazyl halides - NSZ [Z = F, Cl, Br] |
| Authors: | Mayilavelan, S
Ramadasse, S
Balakrishnan, R |
| Keywords: | Three electron bonding
Thiazyl halides |
| Issue Date: | Nov-2004 |
| Publisher: | CSIR |
| IPC Code: | G 09B 23/00 |
| Abstract: | Force fields of NSF, NSCl and NSBr have
been studied employing the iterative force field refinement technique proposed
by the authors in an earlier paper. While the force field of NSF is in
conformity with the structure obtained through the simple electron pairing
approach, those of NSCl and NSBr show deviation. Further, the discrepancy in
the calculated centrifugal distortion constants of NSCl suggests a different
structure. Three-electron bonding seems to be a better proposal for NSCl and
NSBr. A detailed force field-structure analysis is presented on the basis of
three-electron bonding model. |
| Page(s): | 857-862 |
| ISSN: | 0975-1041 (Online); 0019-5596 (Print) |
| Source: | IJPAP Vol.42(11) [November 2004]
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