Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/9244
Title: Polymer-bound cationic Rh(I) phosphine catalyst for homogeneous asymmetric hydrogenation
Authors: Koshti, Nirmal
Naik, Shubhangi
Parab, Bharat
Keywords: Polymer bound Rh(I) phosphine catalyst
homogeneous catalysis
asymmetric hydrogenation
Issue Date: Dec-2005
Publisher: CSIR
Series/Report no.: <b>Int.Cl.<sup>7</sup> C 07 D</b>
Abstract: Facile synthesis of polymer-bound Rh(I) phosphine catalyst which is useful for homogeneous asymmetric hydrogenation is described.Polymer bound Pyrphos Rh(I) complex catalyses hydrogenation of prochiral <i style="">Z</i>-<img src='/image/spc_char/alpha.gif' border=0>-acetamido cinnamic acid to <i style="">S</i>-<i style="">N</i>-acetyl phenyl alanine with 76 % <i>ee</i>.  The polymer bound catalyst is cleanly separated from the product by membrane osmodialysis.
Description: 2555-2559
URI: http://hdl.handle.net/123456789/9244
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.44B(12) December 2005]

Files in This Item:
File Description SizeFormat 
IJCB 44B(12) 2555-2559.pdf112.24 kBAdobe PDFView/Open


Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.