Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/9240
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dc.contributor.authorSingh, Alok-
dc.contributor.authorSikder, Nirmala-
dc.contributor.authorSikder, Arun K-
dc.date.accessioned2010-06-01T05:09:16Z-
dc.date.available2010-06-01T05:09:16Z-
dc.date.issued2005-12-
dc.identifier.issn0975-0983(Online); 0376-4699(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/9240-
dc.description2560-2563en_US
dc.description.abstractTetrahydropyranyl protected 1,3-dihalo-2-propanol reacts with p-toluene sulfonamide in the presence of K2CO3 to give corresponding N-p-tosyl-3-azetidinol. Deprotection and oxidation with iodoxy benzoic acid followed by oximation of N-p-tosyl-3-azetidinone readily affords the corresponding azetidine oxime in almost quantitative yield. The subsequent oxidative nitrolysis of oxime gives 1,3,3-trinitroazetidine (TNAZ) through a new sequence of reactions with excellent purity ( > 99% ) and moderate yield (40% ).en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.relation.ispartofseriesInt.Cl.7 C 07 Den_US
dc.sourceIJC-B Vol.44B(12) December 2005]en_US
dc.subjectTrinitroazetidineen_US
dc.subjectstrained ringen_US
dc.subject2-iodoxy benzoic aciden_US
dc.subjectoximinationen_US
dc.subjectsynthesisen_US
dc.subjectoxidative nitrolysisen_US
dc.subjectinsensiive munitionsen_US
dc.titleImproved synthesis of an energetic material, 1,3,3-trinitroazetidine (TNAZ) exploiting 2-iodoxy benzoic acid (IBX) as an oxidising agenten_US
dc.typeArticleen_US
Appears in Collections:IJC-B Vol.44B(12) December 2005]

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