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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.44B [2005] >
IJC-B Vol.44B(09) [September 2005] >
| Title: | Beckmann rearrangement of ketoximes and deprotection of aldoximes in solvent-free conditions |
| Authors: | Banerjee, Krishna
Mitra, Alok Kumar |
| Keywords: | Beckman rearrangement
ketoximes
deprotection
aldoximes
phosphoric acid amides
lactam
microwave irradiation |
| Issue Date: | Sep-2005 |
| Publisher: | CSIR |
| IPC Code: | Int.Cl.7 C 07 C 251/32 |
| Abstract: | Phosphoric acid is an efficient and mild
reagent for regeneration of aldehyde
from oximes, but ketoximes are converted to amides or lactam by
Beckmann rearrangement.The reactions
are carried out in solvent-free conditions under microwave irradiation. |
| Page(s): | 1876-1879 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.44B(09) [September 2005]
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