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IJC-A Vol.46A(02) [February 2007] >


Title: Photochemical substitution reactions involving nitrosylpentacyanoferrate(II) iodide system using cadmium sulphide as semiconductor
Authors: Chouhan, Mahaveer Singh
Singh, Sadhana
Khandelwal, R C
Issue Date: Feb-2007
Publisher: CSIR
IPC CodeInt. Cl.⁸ B01J19/12
Abstract: Sodium nitroprusside contains cyanide ligands that are not easily replaced chemically. Studies on its substitution reaction with another anionic ligand `iodide’ are reported here. The rate of this photochemical reaction has been studied spectropho-tometrically. The effect of different parameters like pH, inten-sity of light, [sodium nitroprusside] and [iodide] ion on the reac-tion has also been studied. The product has been isolated and characterized by different analytical methods. A tentative mechanism for the photochemical substitution reaction is also proposed.
Page(s): 263-265
ISSN: 0376-4710
Source:IJC-A Vol.46A(02) [February 2007]

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