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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(02) [February 2007] >
| Title: | Photochemical substitution reactions involving nitrosylpentacyanoferrate(II) iodide system using cadmium sulphide as semiconductor |
| Authors: | Chouhan, Mahaveer Singh
Singh, Sadhana
Khandelwal, R C |
| Issue Date: | Feb-2007 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl.⁸ B01J19/12 |
| Abstract: | Sodium nitroprusside contains cyanide ligands that are not easily replaced chemically. Studies on its substitution reaction with another anionic ligand `iodide’ are reported here. The rate of this photochemical reaction has been studied spectropho-tometrically. The effect of different parameters like pH, inten-sity of light, [sodium nitroprusside] and [iodide] ion on the reac-tion has also been studied. The product has been isolated and characterized by different analytical methods. A tentative mechanism for the photochemical substitution reaction is also proposed. |
| Page(s): | 263-265 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(02) [February 2007]
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