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Title: Kinetics of elimination reactions of cumyl chloride and its substituted derivatives in acetonitrile
Authors: Balachandran, S
Kumar, D Santhosh
Keywords: Kinetics;elimination reactions;cumyl chloride;acetonitrile;dehydrochlorination
Issue Date: Aug-2005
Publisher: CSIR
IPC Code: Int.Cl.7 C 07 C // C 07 B 35/06
Abstract: A cent per cent unimolecular elimination reaction of tertiary aralkyl halides in acetonitrile is being reported for the first time. The reversibility in the rate determining step can be prevented by the addition of a weak base like pyridine in cumyl chloride and its α- and p-substituted derivatives. A plot of logarithmic rate constants of α-substituted cumyl chloride against Charton’s steric parameter ‘ν’ gives a linear relationship.
Page(s): 1731-1734
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.44B(08) [August 2005]

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