NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.44B [2005] >
IJC-B Vol.44B(07) [July 2005] >

Title: CeCl3/Sm induced reductive cleavage of the S-S bond in disulfide: A novel method for the synthesis of -thioesters, thiol-esters and alkylphenyl sulfides
Authors: Li, Xue
Zhang, Songlin
Zhang, Yongmin
Keywords: CeCl3/Sm
Issue Date: Jul-2005
Publisher: CSIR
IPC CodeInt.Cl.7 C 07
Abstract: Disulfide has been reduced by cerium trichloride and samarium in tetrahydrofuran to produce samarium thiolates. The “living” species reacts smoothly with ,-unsaturated esters(nitriles) to afford -thioesters(nitrile) under mild and neutral conditions. The new thiolate anion also reacts with acyl halides, anhydrides and alkyl or benzyl halides to give thioesters and sulfides, respectively.
Page(s): 1527-1529
ISSN: 0975-0983(Online); 0376-4699(Print)
Source:IJC-B Vol.44B(07) [July 2005]

Files in This Item:

File Description SizeFormat
IJCB 44B(7) 1527-1529.pdf55.99 kBAdobe PDFView/Open
 Current Page Visits: 629 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 167407 since 01-Sep-2015  Last updated on 28-Jun-2016Webmaster: