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|Title:||CeCl3/Sm induced reductive cleavage of the S-S bond in disulfide: A novel method for the synthesis of -thioesters, thiol-esters and alkylphenyl sulfides|
|IPC Code:||Int.Cl.7 C 07|
|Abstract:||Disulfide has been reduced by cerium trichloride and samarium in tetrahydrofuran to produce samarium thiolates. The “living” species reacts smoothly with ,-unsaturated esters(nitriles) to afford -thioesters(nitrile) under mild and neutral conditions. The new thiolate anion also reacts with acyl halides, anhydrides and alkyl or benzyl halides to give thioesters and sulfides, respectively.|
|Appears in Collections:||IJC-B Vol.44B(07) [July 2005]|
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