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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.44B [2005] >
IJC-B Vol.44B(06) [June 2005] >
| Title: | Dielectric activation of MnO2: Part 1─ Oxidation of conjugated unsaturated alcohols |
| Authors: | Lai, Tapan K
Banerji, Julie
Chatterjee, Asima
Basak, Bidyut |
| Issue Date: | Jun-2005 |
| Publisher: | CSIR |
| IPC Code: | Int.Cl.7 C 07 C 9/00 |
| Abstract: | The activation of ‘wet’ precipitated manganese dioxide through an
environmentally benign and expeditious pathway involving the use of a specially
manoeuvered domestic microwave oven and its applicability in several organic
solvents for near quantitative conversion of a range of conjugated unsaturated
alcohols is demonstrated. The protocol effectively replaces procedures that are
strenuous, hazardous and prohibitively time consuming. Again compatibility in
almost all common organic solvents offers additional advantages e.g. control
over precise activation and remarkable flexibility in the choice of substrates
and conditions. |
| Page(s): | 1309-1311 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.44B(06) [June 2005]
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