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|Title:||Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene|
Ramachary, D B
|IPC Code:||Int.Cl.7 C 07 C 13/10|
|Abstract:||Synthetic approach to 3-alkoxythapsane, comprising of the carbon framework of a small group of sesquiterpenes containing three contiguous quaternary carbon atoms has been described. A combination of alkylation, orthoester Claisen rearrangement and intramolecular diazoketone cyclopropanation has been employed for the creation of the three requisite contiguous quaternary carbon atoms.|
|Appears in Collections:||IJC-B Vol.44B(04) [April 2005]|
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