NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.44B [2005] >
IJC-B Vol.44B(02) [February 2005] >

Title: Preparation of carbamate modified alumina supported heterobinuclear macrocyclic cobalt/vanadium complex for n-octane oxidation reaction
Authors: Kishore, M Jhansi L
Mishra, G S
Kumar, Anil
Issue Date: Feb-2005
Publisher: CSIR
IPC CodeInt.Cl.7 C 07 C 9/14
Abstract: A bimetallic complex CoII VIV L2+ has been synthesized with binucleating macrocyclic ligand prepared by condensing 2 equiv. of 2,6-diformyl-4-methylphenol with 2 equiv. of 1,2-phenylenediamine. This has been immobilized by covalently binding it on a carbamate modified alumina support. The TGA analysis of the final catalyst shows that it is thermally stable up to 251oC and it has been shown that it serves as an oxidation catalyst for n-octane oxidation. During the reaction, there is no change of molecular structure (i.e., absence of cracking or isomerization) and the four oxidative products are 2-octanone (1.5%), 3-octanone (1.2%), octanol (2.6%) and octanoic acid (0.5%) at 150°C.
Page(s): 349-355
ISSN: 0975-0983(Online); 0376-4699(Print)
Source:IJC-B Vol.44B(02) [February 2005]

Files in This Item:

File Description SizeFormat
IJCB 44B(2) 349-355.pdf224.05 kBAdobe PDFView/Open
 Current Page Visits: 70 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 171351 since 01-Sep-2015  Last updated on 30-Jun-2016Webmaster: