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Indian Journal of Pure & Applied Physics (IJPAP) >
IJPAP Vol.43 [2005] >
IJPAP Vol.43(12) [December 2005] >
| Title: | Molecular interaction studies of acrylic esters with alcohols |
| Authors: | Sivagurunathan, P
Dharmalingam, K
Ramachandran, K |
| Keywords: | Molecular interactions
FTIR spectroscopy
Esters
Alcohols
Hydrogen bonding |
| Issue Date: | Dec-2005 |
| Publisher: | CSIR |
| IPC Code: | G01J3/28, C07C231/00 |
| Abstract: | Hydrogen bonding between alcohols and acrylic esters in
benzene has been studied by FTIR spectroscopic method. Utilizing Nash method
the formation constant of the 1:1 complexes has been calculated. The formation
constant and free energy change values vary with alcohol and ester chain
length, which suggests that the proton donating ability of alcohols is in the
order: 1-propanol < 1-butanol < 1-pentanol and the accepting ability of
acrylic esters is in the order: methyl methacrylate < ethyl methacrylate
< butyl methacrylate. |
| Page(s): | 905-910 |
| ISSN: | 0975-1041 (Online); 0019-5596 (Print) |
| Source: | IJPAP Vol.43(12) [December 2005]
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