Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/8759
Title: Titanocene(III) chloride mediated reductive cleavage of arylcyclopropyl ketones
Authors: Paira, M
Mandal, S K
Roy, S C
Keywords: Ti(III) chloride
radical
cyclopropyl ketones
synthesis
aromatic compounds
Issue Date: May-2010
Publisher: CSIR
Abstract: <smarttagtype namespaceuri="urn:schemas-microsoft-com:office:smarttags" name="stockticker"> Titanocene(III) chloride (Cp<sub>2</sub>TiCl) mediated cleavage of arylcyclopropyl ketones has been accomplished. Both saturated and b-H eliminated unsaturated aromatic compounds are formed in different ratio depending on the substrate. Ti(III) species has been prepared <i style="">in situ</i> from commercially available titanocene dichloride (Cp<sub>2</sub>TiCl<sub>2</sub>) and zinc dust in THF. </smarttagtype>
Description: 573-577
URI: http://hdl.handle.net/123456789/8759
Appears in Collections:IJC-B Vol.49B(05) [May 2010]

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