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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.49B [2010] >
IJC-B Vol.49B(05) [May 2010] >
| Title: | Titanocene(III) chloride mediated reductive cleavage of arylcyclopropyl ketones |
| Authors: | Paira, M
Mandal, S K
Roy, S C |
| Keywords: | Ti(III) chloride
radical
cyclopropyl ketones
synthesis
aromatic compounds |
| Issue Date: | May-2010 |
| Publisher: | CSIR |
| Abstract: |
Titanocene(III) chloride (Cp2TiCl)
mediated cleavage of arylcyclopropyl ketones has been accomplished. Both
saturated and b-H eliminated unsaturated aromatic
compounds are formed in different ratio depending on the substrate. Ti(III) species has been prepared in situ from commercially available titanocene dichloride (Cp2TiCl2)
and zinc dust in THF.
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| Page(s): | 573-577 |
| Source: | IJC-B Vol.49B(05) [May 2010]
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