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IJC-B Vol.49B(05) [May 2010] >


Title: Titanocene(III) chloride mediated reductive cleavage of arylcyclopropyl ketones
Authors: Paira, M
Mandal, S K
Roy, S C
Keywords: Ti(III) chloride
radical
cyclopropyl ketones
synthesis
aromatic compounds
Issue Date: May-2010
Publisher: CSIR
Abstract:  Titanocene(III) chloride (Cp2TiCl) mediated cleavage of arylcyclopropyl ketones has been accomplished. Both saturated and b-H eliminated unsaturated aromatic compounds are formed in different ratio depending on the substrate. Ti(III) species has been prepared in situ from commercially available titanocene dichloride (Cp2TiCl2) and zinc dust in THF.
Page(s): 573-577
Source:IJC-B Vol.49B(05) [May 2010]

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