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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.49B [2010] >
IJC-B Vol.49B(05) [May 2010] >
| Title: | Synthesis and semiempirical studies of quinodimethane derivatives as precursors for indigoid dyes |
| Authors: | Pardasani, R T Pardasani, Pushpa Abraham, Ignatious |
| Keywords: | Indigo quinodimethane cyclohexan-1,4-dione dye chromophore |
| Issue Date: | May-2010 |
| Publisher: | CSIR |
| Abstract: | Reaction of cyclohexan-1,4-dione with different
active methylene heterocycles affords tetrahydroquinodimethane derivatives, in
moderate to good yield. Semiempirical calculations indicate that introduction
of double bonds in tetrahydroquinodimethane stabilizes the system due to the
extended conjugation. All the synthesized products have been characterized by
spectral techniques and their conformations ascertained by MO calculations. |
| Page(s): | 561-564 |
| Source: | IJC-B Vol.49B(05) [May 2010]
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