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IJPAP Vol.43(03) [March 2005] >


Title:  Crystal and molecular structure of o-thiobenzyl-N,N-dibenzylaniline (C27H25NS)
Authors: Karmakar, Sanjib
Patowary, Kabita
Bhattacharjee, S K
Talukdar, A N
Keywords: C27H25NS
Van der Walls interactions
Crystal structure of C27H25NS
Molecular structure of C27H25NS
Issue Date: Mar-2005
Publisher: CSIR
IPC CodeC30B
Abstract: In crystals of o-thiobenzyl N,N-dibenzylaniline (I) (C27H25NS), there are three benzyl groups. N atom is two covalent with the C atoms of the two benzyl groups and the S atom is covalent with the C atom of the other benzyl group. The distances N1-C21, N1-C14 and S1-C7 have been found to be 1.489(4), 1.488(9) and 1.832(8)Å, respectively. The molecule is as a whole non-planar. The S1 and the N1 atoms make intramolecular hydrogen bonding. No intermolecular hydrogen bonding has been found and the molecules are stabilised by the network of Van der Waals interaction in their crystalline assembly.
Page(s): 172-174
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Source:IJPAP Vol.43(03) [March 2005]

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