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Title: Ultrasonic investigation of induced dipole-induced dipole interactions in binary liquid mixtures at 298K
Authors: Kannappan, V
Santhi, R Jaya
Keywords: Interactions;Induce dipole;Mole fractions;Polarizability;Adiabatic Compressibility;Ultrasonics;Binary liquid mixtures
Issue Date: Nov-2006
Publisher: CSIR
IPC Code: B01J 19/10
Abstract: Induced dipole-induced dipole interactions have been studied in binary liquid mixtures of benzene, n-hexane, carbon tetra chloride and p-xylene with cyclohexane by ultrasonic velocity (U), density (ρ) and viscosity (η) measurements at 298K and at different mole fractions. Acoustical parameters such as adiabatic compressibility (β), free volume (Vf) internal pressure (i), intermolecular free length (Lf), available volume (νa), cohesive energy (CE) Rao constant (R) and molecular interaction parameter (U) were calculated from the experimental data. The ultrasonic investigations on four binary liquid systems reveal that in the liquid mixture containing non-polar liquids, there exist weak induced dipole-induced dipole attractions. The strength of this type of intermolecular attraction depends on the polarizability of molecules of the components present in the mixture.
Page(s): 815-819
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Appears in Collections:IJPAP Vol.44(11) [November 2006]

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