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Title: Acoustic studies of binary mixtures of N-methylacetamide with some chloroethanes and chloroethenes at 308.15 K
Authors: Sathyanarayana, B
Jyostna, T Savitha
Satyanarayana, N
Keywords: Ultrasonics;Binary mixtures;Chloroethanes;Chloroethenes;N-methylacetamide
Issue Date: Aug-2006
Publisher: CSIR
IPC Code: B01J19/10
Abstract: The densities and speeds of sound of mixtures of 1,2 dichloroethane, 1,1,2 trichloroethane, 1,1,2,2 tetrachloroethane, trichloroethene and tetrachloroethene with N-methylacetamide, over the entire range of composition, have been measured at a temperature of 308.15 K. The deviations in speed Δu, isentropic compressibility ΔkS, intermolecular free-length ΔLF and relative association RA have been computed using speed and density values. The Δu values are negative whereas ΔkS and ΔLF values are positive for all the systems, which indicate the non-specific interactions between unlike molecules. The results are discussed in the light of intermolecular interactions occurring in the solutions. The computed results of ΔkS, have been fitted to a Redlich-Kister type polynomial equation.
Page(s): 587-591
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Appears in Collections:IJPAP Vol.44(08) [August 2006]

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