20-Jun-2013
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NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
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Journal of Scientific and Industrial Research (JSIR) >
JSIR Vol.69 [2010] >
JSIR Vol.69(03) [March 2010] >
| Title: | Synthesis and characterization of methyl nitramino -2, 4, 6-trinitrobenzenes using bismuth nitrate pentahydrate as an eco friendly nitrating agent |
| Authors: | Badgujar, D M
Talawar, M B
Asthana, S N
Mahulikar, P P |
| Keywords: | Bismuth nitrate
Eco-friendly nitration
Microwave irradiation
Nitramines |
| Issue Date: | Mar-2010 |
| Publisher: | CSIR |
| Abstract: | This study presents synthesis of 2,4,6-trinitrophenylmethyl- nitramine (3a) 2,4,6-trinitro-1,3-di(methylnitramino) benzene (3b) and 2,4,6-trinitro-1,3,5-tris(methylnitramino) benzene (3c) by nitration of 2,4,6-trinitro-N-methylaniline (2a), 2,4,6-trinitro- 1,3-di(methylamino) benzene (2b) and 2,4,6-trinitro-1,3,5-tris(methylamino) benzene (2c) using bismuth nitrate pentahydrate in tetrahydrofuran adsorbed on silica gel and fly ash as solid supports under microwave irradiation. An eco-friendly nitration approach used in synthesis of target compounds (3a-3c) is of interest for the production of high energy materials. |
| Page(s): | 208-210 |
| ISSN: | 0975-1084 (Online); 0022-4456 (Print) |
| Source: | JSIR Vol.69(03) [March 2010]
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