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http://nopr.niscair.res.in/handle/123456789/7380
Title: | Synthesis and characterization of methyl nitramino -2, 4, 6-trinitrobenzenes using bismuth nitrate pentahydrate as an eco friendly nitrating agent |
Authors: | Badgujar, D M Talawar, M B Asthana, S N Mahulikar, P P |
Keywords: | Bismuth nitrate;Eco-friendly nitration;Microwave irradiation;Nitramines |
Issue Date: | Mar-2010 |
Publisher: | CSIR |
Abstract: | This study presents synthesis of 2,4,6-trinitrophenylmethyl- nitramine (3a) 2,4,6-trinitro-1,3-di(methylnitramino) benzene (3b) and 2,4,6-trinitro-1,3,5-tris(methylnitramino) benzene (3c) by nitration of 2,4,6-trinitro-N-methylaniline (2a), 2,4,6-trinitro- 1,3-di(methylamino) benzene (2b) and 2,4,6-trinitro-1,3,5-tris(methylamino) benzene (2c) using bismuth nitrate pentahydrate in tetrahydrofuran adsorbed on silica gel and fly ash as solid supports under microwave irradiation. An eco-friendly nitration approach used in synthesis of target compounds (3a-3c) is of interest for the production of high energy materials. |
Page(s): | 208-210 |
URI: | http://hdl.handle.net/123456789/7380 |
ISSN: | 0975-1084 (Online); 0022-4456 (Print) |
Appears in Collections: | JSIR Vol.69(03) [March 2010] |
Files in This Item:
File | Description | Size | Format | |
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JSIR 69(3) 208-210.pdf | 53.56 kB | Adobe PDF | View/Open |
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