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|Title:||Facile ketone sensitized photochemical ring opening of isoxazolidines to β-enaminocarbonyl compounds|
Ishar, Mohan Paul S
|Abstract:||Isoxazolidines, which are otherwise transparent (Pyrex-filter) to UV light, undergo both inter- and intramolecular ketone sensitized photocleavage to furnish β-enaminocarbonyl compounds. A series of experiments on variedly substituted isoxazolidines under different sets of irradiation conditions have been conducted to delineate the mechanistic details, in particular, the photosensitization by carbonyl moiety.|
|Appears in Collections:||IJC-B Vol.49B(02) [February 2010]|
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