|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.46B [2007] >
IJC-B Vol.46B(11) [November 2007] >
| Title: | The electrosynthesis of pinacols |
| Authors: | Jiang Bian, Yan-
Sheng Bai, Dong- |
| Keywords: | Pinacols
Electrosynthesis
Iron
Electrode
Aqueous |
| Issue Date: | Nov-2007 |
| Publisher: | CSIR |
| Abstract: | Electrosynthesis of pinacols by iron as electrode in acid condi-tion is performed. The influence of electric potential and time on pinacol yield is explored. The optimal reaction conditions are at electric potential 4 V, time 60 min., methanol (6 mL), hydrochlo-ric acid (2 N, 2 mL), with the yield of pinacols up to 18-81%. The main advantages of the present procedure are milder reaction conditions and operational simplicity. |
| Page(s): | 1890-1892 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.46B(11) [November 2007]
|
|
