Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/7189
Title: Synthesis and crystal structure of a triprotonated decavanadate, [(C6H5CH2)(CH3)3N]3[H3V10O28].3H2O
Authors: Dewan, Anindita
Kakati, Dilip K
Das, Birinchi K
Keywords: Coordination chemistry
Supramolecular chemistry
Polyoxometallates
Triprotonated decavanadate
Protonated compounds
Hydrogen-bonded chains
X-ray diffraction
Crystal structure
Vanadium
Issue Date: Jan-2010
Publisher: CSIR
Series/Report no.: Int. Cl.9 C07F9/00
Abstract: The title compound, [(C6H5CH2)(CH3)3N]3[H3V10O28].3H2O, has been obtained by treating V2O5 with H2O2 in presence of benzyltrimethylammonium chloride and characterised. The crystal structure of the compound has been determined. The protonation sites on the cage surface of the decavanadate [H3V10O28]3- anion have been clearly identified. Intermolecular O-H...O hydrogen bonds involving the surface protons leads to the formation of an unprecedented zigzag chain of the [H3V10O28]3- anions.
Description: 39-44
URI: http://hdl.handle.net/123456789/7189
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.49A(01) [January 2010]

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