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dc.contributor.authorRaj, M A Lourdu Antony-
dc.contributor.authorMadhu, G M-
dc.contributor.authorRao, Y Jagannadha-
dc.date.accessioned2009-12-31T09:23:56Z-
dc.date.available2009-12-31T09:23:56Z-
dc.date.issued2006-03-
dc.identifier.issn0975-0991 (Online); 0971-457X (Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/7007-
dc.description107-113en_US
dc.description.abstractCatalytic partial oxidation of methane to methanol has been investigated in a pressures range of 5-15 kg/cm² and at different temperatures (573-763 K) in quartz-lined reactor using asbestos supported palladium catalyst. The effect of process variables namely, reaction temperature, ratio of the weight of the catalyst to molar flow rate of methane (W/FA0), pressure on conversion of methane and selectivity to reaction products like methanol, carbon dioxide, carbon monoxide were investigated. The kinetic study carried out indicated first order rate for the main reactions. From the effect of temperature on rate constant, activation energy and frequency factors were evaluated. The rate constants are found to be 2.53 and 1.84, activation energies are found to be 186948.60 and 162231.08 for the two main reactions.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.relation.ispartofseriesB01J19/00en_US
dc.sourceIJCT Vol.13(2) [March 2006]en_US
dc.subjectPartial oxidationen_US
dc.subjectCatalytic oxidationen_US
dc.subjectMethaneen_US
dc.subjectMethanolen_US
dc.subjectPalladiumen_US
dc.titleKinetics of palladium catalysed partial oxidation of methaneen_US
dc.typeArticleen_US
Appears in Collections:IJCT Vol.13(2) [March 2006]

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