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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.46B [2007] >
IJC-B Vol.46B(09) [September 2007] >
| Title: | Exploratory studies towards AB-ring system of taxanes via intramolecular alkylation reaction. Formation of bicyclo[2.2.2]octanones in preference to bicyclo[5.3.1]undecanes |
| Authors: | Srikrishna, A
Reddy, T Jagadeeswara
Kumar, P Praveen |
| Keywords: | Taxanes
Intramolecular alkylation
Bicyclo[5.3.1]undecanes
Carvone
Bicyclo[2.2.2]octanes |
| Issue Date: | Sep-2007 |
| Publisher: | CSIR |
| Abstract: | An intramolecular alkylation based approach has been explored for the enantiospecific construction of AB-ring system of taxanes starting from 3-allyl-4,4-dimethylcarvone, which however led only to bicyclo[2.2.2]octanones. |
| Page(s): | 1518-1525 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.46B(09) [September 2007]
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