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IJC-B Vol.45B(12) December 2006] >


Title: Kinetics of elimination reactions of 1-chloro-1-(4-methoxyphenyl)-2-phenylethane in acetonitrile
Authors: Kumar, D Santhosh
Balachandran, S
Keywords: Kinetic study
elimination reaction
dehydrochl-orination
phenylethane
trans-p-methoxy stilbene
acetonitrile
Issue Date: Dec-2006
Publisher: CSIR
IPC CodeInt.Cl.8 C07D
Abstract: 1-Chloro-1-(4-methoxyphenyl)-2-phenylethane undergoes dehydrochlorination in acetonitrile to give trans-p-methoxy stilbene by E1 mechanism. The presence of electron donating p-methoxy group and the delocalisation of charge throughout the structure proposes a stable cation. The mass law effect and special salt effect are characteristic for a reaction involving the stable cation and these effects have been reported for the first time in a pure E1 reaction.
Page(s): 2751-2753
ISSN: 0975-0983(Online); 0376-4699(Print)
Source:IJC-B Vol.45B(12) December 2006]

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