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Title: A simple synthesis of <img src='/image/spc_char/alpha.gif' border=0>-methyl-<img src='/image/spc_char/gamma2.gif' border=0>-keto acids
Authors: Pawar, B V
Waghmare, B Y
Lokhande, P D
Keywords: Morpholinoacetonitrile
<img src='/image/spc_char/gamma2.gif' border=0>-keto acids
conjugate addition
enolate alkylation
Issue Date: Nov-2006
Publisher: CSIR
Series/Report no.: Int. Cl.<sup>8</sup> C07C
Abstract: The reaction of the anion derived from <img src='/image/spc_char/alpha.gif' border=0>-marpholinonitriles with methyl acrylate in excess of NaH in DMF gives <img src='/image/spc_char/gamma2.gif' border=0>-keto acids in high yield. This process is highly convenient for the synthesis of various <img src='/image/spc_char/alpha.gif' border=0>-substituted-<img src='/image/spc_char/gamma2.gif' border=0>-keto acids, which can be easily converted to naturally occurring <img src='/image/spc_char/alpha.gif' border=0>-substituted-<img src='/image/spc_char/gamma2.gif' border=0>-lactones.
Description: 2549-2551
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(11) [November 2006]

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