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|Title:||Selective binding of benzoquinone with a PtII-cyclophane constructed on the skeleton of N,N'-bis(salicylidene)-p-phenylenediamine: Synthesis and spectroscopic studies|
|Series/Report no.:||Int. Cl.9 CO7F15/00; CO7C251/02|
|Abstract:||The Schiff base N,N'-bis(salicylidene)-p-phenylenediamine has been complexed with Pt(en)Cl2 and the resulting PtII-cyclophane, [Pt(en)L]2·4PF6, reacted with phenol, resorcinol, hydroquinone or benzoquinone in DMSO solution. Their binding has been monitored by the variation in the corresponding UV-visible and emission spectral patterns. The binding properties are compared with the earlier reported ZnII-cyclophane [Zn(bpy)L]2 (bpy = 2,2'-bipyridine). A few solid adducts of phenol and benzoquinone with the PtII-cyclophane complex and hydroquinone as well as that of resorcinol with the Zn-cyclophane have also been synthesized and characterized.|
|Appears in Collections:||IJC-A Vol.48A(12) [December 2009]|
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