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Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.46B [2007] >
IJC-B Vol.46B(08) [August 2007] >
| Title: | An RCM based approach to (±)-herbertene-1, 14-diol and (±)-tochuinyl acetates |
| Authors: | Srikrishna, A
Rao, M Sreenivasa |
| Keywords: | Terpene synthesis
Vicinal quaternary carbons
Claisen rearrangement
Ring-closing metathesis
Herbertanes
Cuparanes |
| Issue Date: | Aug-2007 |
| Publisher: | CSIR |
| Abstract: | A sequence comprising of Johnson's ortho ester Claisen rearrangement, alkylation and RCM reactions has been developed for the synthesis of cyclopentenes containing vicinal quaternary carbon atoms. The versatility of the sequence has been demonstrated by the efficient total synthesis of sesquiterpenes tochuinyl acetates and herbertene-1,14-diol. |
| Page(s): | 1308-1317 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.46B(08) [August 2007]
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