Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/673
Title: An RCM based approach to (±)-herbertene-1, 14-diol and (±)-tochuinyl acetates
Authors: Srikrishna, A
Rao, M Sreenivasa
Keywords: Terpene synthesis
Vicinal quaternary carbons
Claisen rearrangement
Ring-closing metathesis
Herbertanes
Cuparanes
Issue Date: Aug-2007
Publisher: CSIR
Abstract: A sequence comprising of Johnson's ortho ester Claisen rearrangement, alkylation and RCM reactions has been developed for the synthesis of cyclopentenes containing vicinal quaternary carbon atoms. The versatility of the sequence has been demonstrated by the efficient total synthesis of sesquiterpenes tochuinyl acetates and herbertene-1,14-diol.
Description: 1308-1317
URI: http://hdl.handle.net/123456789/673
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.46B(08) [August 2007]

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