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Title: An RCM based approach to (±)-herbertene-1, 14-diol and (±)-tochuinyl acetates
Authors: Srikrishna, A
Rao, M Sreenivasa
Keywords: Terpene synthesis;Vicinal quaternary carbons;Claisen rearrangement;Ring-closing metathesis;Herbertanes;Cuparanes
Issue Date: Aug-2007
Publisher: CSIR
Abstract: A sequence comprising of Johnson's ortho ester Claisen rearrangement, alkylation and RCM reactions has been developed for the synthesis of cyclopentenes containing vicinal quaternary carbon atoms. The versatility of the sequence has been demonstrated by the efficient total synthesis of sesquiterpenes tochuinyl acetates and herbertene-1,14-diol.
Page(s): 1308-1317
ISSN: 0376-4699
Appears in Collections:IJC-B Vol.46B(08) [August 2007]

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