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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.45B [2006] >
IJC-B Vol.45B(09) [September 2006] >
| Title: | Synthesis of novel calix[4]arenes containing one and two substituents on the “upper rim” |
| Authors: | Lei, Li Ping, Lv chunying, Xian Limin, Zheng |
| Keywords: | p-tert-Butylcalix[4]arene upper rim monomers polymer |
| Issue Date: | Sep-2006 |
| Publisher: | CSIR |
| IPC Code: | Int Cl.8 C07C |
| Abstract: | Procedures are described for the removal of the p-butyl groups from p-tert-butylcalix[4]arene and the introduction of benzoyl, nitro, amino and acrylamido groups to yield a series of mono- and bis-substituted compounds on the “upper rim” with potential possibility to polymerized with other monomers. These compounds have been characterized by IR, 1H NMR, elemental analysis and ESI-MS. As the upper rim of the calix[4]arene, which has the site group of polymerization, can be linked into the chains of the polyimides, the ultimate goal of the project is to find a new application for the well established binding properties of calix[4]arene and to develop polyimides that are suitable for the recovery of metal ions from waste water, gas separation and ion-specific electrodes. |
| Page(s): | 2118-2122 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.45B(09) [September 2006]
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