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IJC-B Vol.45B [2006] >
IJC-B Vol.45B(09) [September 2006] >

Title: Effect of organized assemblies, Part-III: Micellar catalysed iodo-de-diazoniation reactions
Authors: Mishra, H P
Panigrahi, S
Misra, Pramila K
Behera, G B
Keywords: Iodobenzene
iodo-de-diazoniation reaction
surfactant assisted reactions
Menger’s model
green chemistry
hydrophobic patches
Issue Date: Sep-2006
Publisher: CSIR
IPC CodeInt. Cl.8 C07C
Abstract: The iodo-de-diazoniation of benzene diazonium chloride has been carried out in the presence of ionic and nonionic surfactants. Anionic and nonionic micelles do not facilitate the product formation whereas the cationic surfactant gives a reasonable increase in the yield as compared to that in the absence of the surfactants. The results have been attributed to the increase in the effective concentration of the reactants in a reduced volume of Menger’s micelle resulting out of both hydrophobic and electrostatic interaction of the reactants and the micelle.
Page(s): 2140-2142
ISSN: 0975-0983(Online); 0376-4699(Print)
Source:IJC-B Vol.45B(09) [September 2006]

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