Please use this identifier to cite or link to this item:
Title: A new route to the synthesis of long-chain methyl -chlorooxoalkanoates
Authors: Rauf, Abdul
Ahmad, Shabana
Keywords: Methyl epoxyalkanoates;chlorotrimethylsilane;Jones′ oxidation;methyl -chlorooxoalkanoates
Issue Date: Aug-2006
Publisher: CSIR
IPC Code: Int.Cl.8 C07C
Abstract: A reaction of long-chain methyl epoxyalkanoates with chlorotrimethylsilane in presence of triethylamine followed by Jones oxidation has resulted in the formation of respective chlorooxo derivatives. The reaction proceeds under mild conditions and in a short span of time. Thus, one pot synthesis of methyl chlorooxoalkanoates is assisted with high purity and good yield of the products. The pure products are characterized by IR, 1H NMR, 13C NMR and MS spectra.
Page(s): 1924-1928
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(08) [August 2006]

Files in This Item:
File Description SizeFormat 
IJCB 45B(8) 1924-1928.pdf155.86 kBAdobe PDFView/Open

Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.