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http://nopr.niscair.res.in/handle/123456789/6639| Title: | Synthesis of N-hydroxy-r-2,c-6-diphenylpiperidines using DMD and their stereochemical studies by NMR spectra and semiempirical MO calculations |
| Authors: | Thenmozhiyal, J C Venkatraj, M Jeyaraman, R Ponnuswamy, S |
| Keywords: | Dimethyldioxirane diphenylpiperidine conformation MO calculation |
| Issue Date: | Aug-2006 |
| Publisher: | CSIR |
| Series/Report no.: | Int. Cl.8 C07D |
| Abstract: | r-2,c-6-Diphenylpiperidin-4-ones 2-6 and r-2,c-6-diphenylpiperidine 7 are treated with DMD and the reaction is found to yield only the corresponding N-hydroxy derivatives 8-13. The preferred conformations of the N-hydroxy compounds 8-13 are analysed using the NMR spectra and semiempirical molecular orbital calculations. The N-hydroxy derivatives 8-13 are found to prefer distorted chair conformations. |
| Description: | 1887-1893 |
| URI: | http://hdl.handle.net/123456789/6639 |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Appears in Collections: | IJC-B Vol.45B(08) [August 2006] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCB 45B(8) 1887-1893.pdf | 102.05 kB | Adobe PDF | View/Open |
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