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IJC-B Vol.45B(08) [August 2006] >


Title: An enantiospecific synthesis of 2-pupukeanone
Authors: Srikrishna, A
Kumar, P Ravi
Gharpure, S J
Keywords: Pupukeananes
marine sesquiterpenes
Michael-Michael reaction
rhodium carbenoid
intramolecular CH-insertion
Issue Date: Aug-2006
Publisher: CSIR
IPC CodeInt. Cl.8 C07C
Abstract: A combination of intermolecular Michael addition followed by intramolecular Michael addition of an enone to methyl acrylate and an intramolecular rhodium carbenoid CH insertion reaction of a diazo ketone have been exploited for the construction of isotwistanes. It has been extended to racemic and enantiospecific synthesis of 2-pupukeanone.
Page(s): 1909-1919
ISSN: 0975-0983(Online); 0376-4699(Print)
Source:IJC-B Vol.45B(08) [August 2006]

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