Please use this identifier to cite or link to this item:
Title: An enantiospecific synthesis of 2-pupukeanone
Authors: Srikrishna, A
Kumar, P Ravi
Gharpure, S J
Keywords: Pupukeananes;marine sesquiterpenes;Michael-Michael reaction;rhodium carbenoid;intramolecular CH-insertion
Issue Date: Aug-2006
Publisher: CSIR
IPC Code: Int. Cl.8 C07C
Abstract: A combination of intermolecular Michael addition followed by intramolecular Michael addition of an enone to methyl acrylate and an intramolecular rhodium carbenoid CH insertion reaction of a diazo ketone have been exploited for the construction of isotwistanes. It has been extended to racemic and enantiospecific synthesis of 2-pupukeanone.
Page(s): 1909-1919
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(08) [August 2006]

Files in This Item:
File Description SizeFormat 
IJCB 45B(8) 1909-1919.pdf173.09 kBAdobe PDFView/Open

Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.