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IJC-A Vol.48A(11) [November 2009] >


Title: Synthesis and characterization of complexes of Fe(III), Co(III), Ni(II), Cu(II), Zn(II) and UO22+ with p-tert-butylcalix[4]arene bearing two imine pendants linked through salicylyl moiety at the lower rim
Authors: Dey, Mishtu
Chinta, Jugun Prakash
Long, Gary J
Rao, Chebrolu P
Keywords: Coordination chemistry
Calixarenes
Calix[4]arene-imine conjugates
Iron
Cobalt
Nickel
Copper
Zinc
Uranium
FAB mass spectrometry
Magnetic susceptibility
Electron paramagnetic resonance
Mossbauer spectroscopy
Issue Date: Nov-2009
Publisher: CSIR
IPC CodeInt. Cl.9 C07F1/08; C07F3/06; C07F5/00; C07F15/00
Abstract: Metal ion complexes of the double-armed p-tert-butylcalix[4]arene derivative possessing imine functionality linked through salicylyl moiety  at the lower rim has been synthesized for the first time and characterized by analytical, spectral and magnetic methods. The 1, 3- di-calix[4]arene-imine conjugate exhibits variable coordination behavior, from tetradentate to hexadentate, depending upon the metal ion to which it is bound, by always acting as di-anionic. While it uses both the ether oxygens of the pendants to coordinate in the case of Fe(III), Co(III) and Ni(II) complexes, it uses only the pendant salicylidene moieties in the case of Cu(II) and Zn(II) complexes. The Zn(II) complex catalysis ester hydrolysis through the formation of Zn(II)-hydroxo species.
Page(s): 1484-1491
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.48A(11) [November 2009]

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