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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.48A [2009] >
IJC-A Vol.48A(11) [November 2009] >
| Title: | Palladium assisted formation of arylselenoacetone from diaryldiselenides in methanol-acetone |
| Authors: | Ghavale, Ninad
Wadawale, Amey
Dey, Sandip
Jain, Vimal K |
| Keywords: | Coordination chemistry
Palladium
Selenium
Ketones
X-ray diffraction
Photoelectron spectroscopy |
| Issue Date: | Nov-2009 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl.9 C07F15/00 |
| Abstract: | The reaction of Na2PdCl4
with diaryldiselenide in
methanol-acetone yields trans-[PdCl2{SeAr(CH2COMe)}2]
(Ar = 2,4,6-Me3C6H2 and 2,4,6-iPr3C6H2)
and [PdCl(SeAr)]n. The intermediate
products in these reactions have been characterized by analytical and
spectroscopic data and by single crystal X-ray diffraction studies. A plausible
mechanism for the formation of arylselenoacetone in these reactions has been
suggested. |
| Page(s): | 1510-1514 |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Source: | IJC-A Vol.48A(11) [November 2009]
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