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Title: Palladium assisted formation of arylselenoacetone from diaryldiselenides in methanol-acetone
Authors: Ghavale, Ninad
Wadawale, Amey
Dey, Sandip
Jain, Vimal K
Keywords: Coordination chemistry
X-ray diffraction
Photoelectron spectroscopy
Issue Date: Nov-2009
Publisher: CSIR
Series/Report no.: Int. Cl.<sup>9</sup> C07F15/00
Abstract: The reaction of Na<sub>2</sub>PdCl<sub>4</sub> with diaryldiselenide in methanol-acetone yields <i style="">trans</i>-[PdCl<sub>2</sub>{SeAr(CH<sub>2</sub>COMe)}<sub>2</sub>] (Ar = 2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub> and 2,4,6-<i style="">i</i>Pr<sub>3</sub>C<sub>6</sub>H<sub>2</sub>) and [PdCl(SeAr)]<sub>n</sub>. The intermediate products in these reactions have been characterized by analytical and spectroscopic data and by single crystal X-ray diffraction studies. A plausible mechanism for the formation of arylselenoacetone in these reactions has been suggested.
Description: 1510-1514
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.48A(11) [November 2009]

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