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Title: Palladium assisted formation of arylselenoacetone from diaryldiselenides in methanol-acetone
Authors: Ghavale, Ninad
Wadawale, Amey
Dey, Sandip
Jain, Vimal K
Keywords: Coordination chemistry;Palladium;Selenium;Ketones;X-ray diffraction;Photoelectron spectroscopy
Issue Date: Nov-2009
Publisher: CSIR
IPC Code: Int. Cl.9 C07F15/00
Abstract: The reaction of Na2PdCl4 with diaryldiselenide in methanol-acetone yields trans-[PdCl2{SeAr(CH2COMe)}2] (Ar = 2,4,6-Me3C6H2 and 2,4,6-iPr3C6H2) and [PdCl(SeAr)]n. The intermediate products in these reactions have been characterized by analytical and spectroscopic data and by single crystal X-ray diffraction studies. A plausible mechanism for the formation of arylselenoacetone in these reactions has been suggested.
Page(s): 1510-1514
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.48A(11) [November 2009]

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